The fall and rise of metropolitan government in Copenhagen     

Hans Thor Andersen  Frank Hansen  John Jørgensen 《GeoJournal》2002,58(1):43-52

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes     

N. R. J. Poolton  K. B. Ozanyan  J. Wallinga  A. S. Murray  L. Bøtter-Jensen 《Physics and Chemistry of Minerals》2002,29(3):217-225

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001  相似文献   

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO₄ system     

Ivan L’Heureux  Bjørn Jamtveit 《Geochimica et cosmochimica acta》2002,66(3):417-429

Barite-celestite crystals can be synthesized from aqueous solutions during counter-diffusion in a gel column connecting two reservoirs. It is known that such crystals may exhibit oscillatory zoning, whereby the barium composition in the crystal fluctuates more or less regularly from the core of the crystal to its rim. We present here a simple model of oscillatory zoning in such binary solid solutions A₁A₂ grown from aqueous solutions. The model combines diffusive transport of the relevant ions with an autocatalytic growth process. The latter is formulated as a continuous growth in which the probability of finding a kink site on the growing surface depends on the chemical composition of that surface. Thus, an A₁-rich surface favors the growth of A₁ over A₂, as long as A₁ is present in the vicinity of the surface. Precipitation results in a local depletion of A₁ in the aqueous solution, and the system may switch to a A₂ growth mode, until diffusion replenishes the amount of A₁, and so on. We use a dynamical equation for the molar fraction of component A₁ in the crystal, which results from mass conservation across the rough crystal-solution interface. Linear stability analysis and direct numerical solutions show that the system exhibits oscillatory behavior. Using the barite-celestite system as a framework, the scaling is consistent with the experimental observations. We discuss the variety of zoning patterns and textures numerically obtained as the concentrations of reactants in the reservoirs vary. This model might help in understanding the formation of oscillatory zoning in hydrothermal environments.  相似文献   

Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications     

Bradley D. Eyre  Søren Rysgaard  Tage Dalsgaard  Peter Bondo Christensen 《Estuaries and Coasts》2002,25(6):1077-1087

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.  相似文献   

Phytoplankton, nutrients, and transparency in Danish coastal waters     

Søren Laurentius Nielsen  Kaj Sand-Jensen  Jens Borum  Ole Geertz-Hansen 《Estuaries and Coasts》2002,25(5):930-937

We present a comparative analysis of 1400 data series of water chemistry (particularly nitrogen and phosphorus concentrations), phytoplankton biomass as chlorophylla (chla) concentrations, concentrations of suspended matter and Secchi depth transparency collected from the mid-1980s to the mid-1990s from 162 stations in 27 Danish fjords and coastal waters. The results demonstrate that Danish coastal waters were heavily eutrophied and had high particle concentrations and turbid waters. Median values were 5.1 μg chla 1⁻¹, 10.0 mg DW 1⁻¹ of suspended particles, and Secchi depth of 3.6 m. Chlorophyll concentration was strongly linked to the total-nitrogen concentration. The strength of this relationship increased from spring to summer as the concentration of total nitrogen declined. During summer, total nitrogen concentrations accounted for about 60% of the variability in chlorophyll concentrations among the different coastal systems. The relationship between chlorophyll and total phosphorus was more consistant over the year and correlations were much weaker than encountered for total nitrogen. Secchi depth could be predicted with good precision from measurements of chlorophyll and suspended matter. In a multiple stepwise regression model with In-transformed values the two variables accounted for most of the variability in water transparency for the different seasons and the period March–October as a whole (c. 80%). We were able to demonstrate a significant relationship between total nitrogen and Secchi depth, with important implications for management purposes.  相似文献   

Wave velocities and attenuation of shaley sandstones as a function of pore pressure and partial saturation   总被引：3，自引：0，他引：3  

Nam H. Pham  †  José M. Carcione  Hans B. Helle  Bjørn Ursin 《Geophysical Prospecting》2002,50(6):615-627

We obtain the wave velocities and quality factors of clay‐bearing sandstones as a function of pore pressure, frequency and partial saturation. The model is based on a Biot‐type three‐phase theory that considers the coexistence of two solids (sand grains and clay particles) and a fluid mixture. Additional attenuation is described with the constant‐Q model and viscodynamic functions to model the high‐frequency behaviour. We apply a uniform gas/fluid mixing law that satisfies the Wood and Voigt averages at low and high frequencies, respectively. Pressure effects are accounted for by using an effective stress law. By fitting a permeability model of the Kozeny– Carman type to core data, the model is able to predict wave velocity and attenuation from seismic to ultrasonic frequencies, including the effects of partial saturation. Testing of the model with laboratory data shows good agreement between predictions and measurements.  相似文献   

Mesoscale transport of air pollution     

Jørgen Brandt  Torben Mikkelsen 《Physics and Chemistry of the Earth》2002,27(35):1467

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Comparison of Seismic Dispersion and Attenuation Models   总被引：2，自引：0，他引：2  

Ursin  Björn  Toverud  Tommy 《Studia Geophysica et Geodaetica》2002,46(2):293-320

The frequency-dependent attenuation of seismic waves causes decreased resolution of seismic images with depth, and the difference in transmission losses induces amplitude variations with offset. Transmission losses may occur due to friction or fluid movement, or may result from scattering in thin-layer. Whatever the physical mechanism, they can often be conveniently described using an empirical formulation wherein the elastic moduli and propagation velocity are complex functions of frequency.We have compiled and compared algebraically and numerically eight different models involving complex velocity: the Kolsky-Futterman model, the power-law model, Kjartansson's model, Müller's model, Azimi's second and third model, the Cole-Cole model, and the standard linear-solid model.For two different parameter sets, the attenuation and phase velocity are computed in the seismic frequency band, and the plane-wave propagation of a Ricker wavelet for the other models is compared with that for the Kolsky-Futterman model. The first parameter set consists of parameters for each of the models calculated from expressions given in the appendix. These expressions make the different models behave similarly to the KF model. The second parameter set consists of model parameters that are numerically adapted to the KF model.By selecting proper parameters, all models, except the standard linear-solid model, show behavior similar to that of the Kolsky-Futterman model. The SLS model behaves differently from the other models as the frequency goes to zero or infinity. Broadband measurement data is needed to select a specific model for a given seismic experiment.  相似文献   

Erratum: Comparison of Seismic Dispersion and Attenuation Models: Stud. Geophys. Geod., 46(2002), 293-320     

Ursin  Björn  Toverud  Tommy 《Studia Geophysica et Geodaetica》2002,46(4):809-809

Studia Geophysica et Geodaetica -  相似文献   

Estimates of lichen growth–rate in northern Sweden     

Wibjörn Karlén  & Jessica L. Black 《Geografiska Annaler: Series A, Physical Geography》2002,84(3&4):225-232

Two lichenometric techniques were compared in a study of lichen growth–rate in northern Sweden. The first technique, based on the maximum lichen diameter on glacier moraines, was identical to the technique used in the 1970s, whereas the other utilized the lichen diameter measured on 100 randomly selected boulders. The results indicate that it does not matter which technique is chosen, as long as the technique is used consistently on both the calibration surfaces and the surfaces to be dated. The use of data from both the 1970s and the 2000s increased the number of calibration surfaces available. The new calibration curve indicates that the age of Little Ice Age moraines was underestimated by up to about 30 years in the study conducted in the 1970s.  相似文献